T53805

Image

1 of 1


T53805

Aldrich

 

Trichloroacetonitrile

98%

CAS Number:545-06-2
Linear Formula:Cl3CCN
Molecular Weight:144.39
Beilstein Registry Number:605572
EC Number:208-885-7
MDL number:MFCD00001842
PubChem Substance ID:24900271

Details

Related Products

References

Reviews

Description

ApplicationEmployed in a synthesis of trichloroacetimidates by DBU catalyzed addition of allylic alcohols and the subsequent study of the MOM catalyzed aza-Claisen rearrangement.1 Also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines via acid catalyzed cyclization.2
Packaging5, 100, 500 g in glass btl

Properties

vapor pressure58 mmHg ( 20 °C)
assay98%
refractive indexn20/D 1.441(lit.)
bp83-84 °C(lit.)
density1.44 g/mL at 25 °C(lit.)

Safety

Personal Protective EquipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard CodesT,N
Risk Statements23/24/25-51/53
Safety Statements45-61
RIDADRUN3276 6.1/PG 3
WGK Germany3
RTECSAM2450000
Flash Point(F)383 °F
Flash Point(C)195 °C

References

Cited Reference1. Tet. 63, 2123, (2007)
 2. Org. Lett. 9, 247, (2007) Abstract
MerckMerck 13,9701
BeilsteinBeil. 2,IV,524
FieserFieser 1,1194 / Fieser 5,686 / Fieser 6,604 / Fieser 7,381 / Fieser 12,526 / Fieser 13,321
referenceAldrich MSDS 1, 1734:A / Corp MSDS 1 (2), 3405:D / FT-IR 1 (1), 848:C / FT-IR 2 (1), 1438:A / FT-NMR 1 (1), 1367:B / IR-Spectra (2), 449:H / IR-Spectra (3), 506:E / RegBook 1 (1), 997:B / Sax 6, 2617 / Structure Index 1, 155:D:6 / Vapor Phase 3, 807:A